Gottfried Wilhelm Ehrenstein
Polymeric Materials
Structure, Properties, Applications
Preface
6
Table of Contents
8
Nomenclature
12
Abbreviations for Plastics
17
1 Economic Development – Market Review and Predictions
20
2 General Characteristics of Polymeric Materials
32
2.1 Principles of Structure
32
2.2 Material States and Transition Regions
35
2.3 Deformation Behavior
39
2.4 Literature
43
3 Molecular Structure and Synthesis of Polymers
44
3.1 Macromolecular Structure
44
3.2 Primary and Secondary Valence Bonds
50
3.3 Reactions from Monomers to Polymers
55
3.4 Literature
77
4 Structure of Polymeric Materials
80
4.1 Homogeneous Polymeric Materials
80
4.2 Heterogeneous Polymeric Materials
117
4.3 Heterogeneous Composites
135
4.4 Literature
159
5 Thermomechanical Properties
162
5.1 Glassy or Energy-Elastic Region
165
5.2 Rubbery or Entropy-Elastic Region
167
5.3 Glass Transition Range
171
5.4 Flow Region
176
5.5 Dependence of Softening and Melting Temperatures onMolecular Structure
178
5.6 Literature
184
6 Mechanical Behavior
186
6.1 General Deformation Behavior
186
6.2 Orientation and Residual Stress
233
6.3 Literature
246
7 Aging and Stabilization
248
7.1 Aging
248
7.2 Exposure to Heat
250
7.3 Stabilization
257
7.4 Literature
259
8 Overview of Selected Polymeric Materials
260
9 Guide Values of the Physical Properties of Plastics
279
Subject Index
288
The Author
297
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